Why can't energy conservation alone say where the object leaves the sphere, and what fixes the angle at arccos(2/3)?
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A normal force perpendicular to the displacement does no work
Record that energy conservation alone carries no constraint from this force, and write the radial component in polar coordinates.
The separation constraint
Set in the radial equation and write the resulting relation between the speed at separation and the angle from the vertical.
The results and
Take at the sphere's centre, write , substitute the constraint, and solve for the angle and then the speed.