Where does mechanical energy go when path-dependent forces act, and how does W_ext + Q = ΔE_sys become the first law of thermodynamics?
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Split , substitute and , and rearrange to the stated result for path-dependent internal forces.
Irreversible processes and non-recoverable energy
State and record the definition of an irreversible process as one with nonzero non-recoverable energy.
First law
Write , then the first law, and tabulate the sign convention for and in both directions, in joules.